合肥工业大学校徽

合肥工业大学学报自科版

合肥工业大学学报(自然科学版)

JOURNAL OF HEFEI UNIVERSITY OF TECHNOLOGY (NATURAL SCIENCE)

主管：中华人民共和国教育部

主办：合肥工业大学

ISSN 1003-5060, CN 34-1083/N

$ SiO_{2}-TiO_{2} $ 复合膜在染料敏化太阳能电池中的应用

Application of $ SiO_{2}-TiO_{2} $ composite film in dye-sensitized solar cells

期刊信息

合肥工业大学（自然科学版），2023年9月，第46卷第9期：1185-1190

DOI: 10.3969/j.issn.1003-5060.2023.09.006

作者信息

牛海红，邵军

（合肥工业大学电气与自动化工程学院，安徽合肥230009）

摘要和关键词

摘要: 文章通过 Stöber 法合成粒径为 300 nm 的 $ SiO_{2} $ 纳米球, 将该纳米球以乙醇为溶剂配置成一定浓度的悬浮液, 通过旋涂法使其在染料敏化太阳能电池 (dye-sensitized solar cells, DSSCs) 的光阴极 P25 上形成一层薄膜, 再将形成的 P25- $ SiO_{2} $ 复合膜放入 $ TiO_{2} $ 溶胶中浸泡一定时间, 使得光阴极上的 $ SiO_{2} $ 纳米球被 $ TiO_{2} $ 纳米粒子包裹, 形成 $ SiO_{2}-TiO_{2} $ 核壳结构薄膜。与没有散射层的 DSSCs 相比, 以该核壳结构薄膜作为 DSSCs 的光散射层电池的光电转换效率提高了 18%。

关键词: $ SiO_{2} $ 纳米球；旋涂法； $ SiO_{2}-TiO_{2} $ 核壳结构薄膜；散射层；染料敏化太阳能电池（DSSCs）光阳极

Authors

NIU Haihong, SHAO Jun

(School of Electrical Engineering and Automation, Hefei University of Technology, Hefei 230009, China)

Abstract and Keywords

Abstract: In this paper, Stöber method was applied to synthesizing 300 nm $ SiO_{2} $ nanospheres, which was dissolved in absolute ethyl alcohol to form a suspension liquid containing various concentrations. A nano-film was fabricated by coating $ SiO_{2} $ suspension liquid on P25 photoanode of dye-sensitized solar cells (DSSCs) via spin coating method. Then, the P25- $ SiO_{2} $ composite film was immersed in the $ TiO_{2} $ sol for a certain time. Therefore, the $ SiO_{2} $ nanospheres on P25 photoanode were packed by $ TiO_{2} $ nanoparticles and a film containing core-shell structure was obtained. When the $ SiO_{2}-TiO_{2} $ core-shell structure film was employed as the scattering layer of DSSCs, the efficiency of cells increases 18% compared with that of the DSSCs without the scattering layer.

Keywords: $ SiO_{2} $ nanosphere; spin coating method; $ SiO_{2}-TiO_{2} $ core-shell structure film; scattering layer; dye-sensitized solar cells (DSSCs) photoanode

基金信息

国家自然科学基金青年科学基金资助项目（51802067）

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