DOI:10.3969/j.issn.1003-5060.2023.02.014
基于岩棉的超亲水/水下疏油过滤材料的制备及在油水分离中的应用
聂伟,童庆东,许健,李倩倩,王强英,杨文
(合肥工业大学化学与化工学院,安徽合肥230009)
摘要
文章以岩棉为基质,通过一步光引发聚合方法在岩棉纤维表面引入亲水性聚丙烯酰胺,成功制备了油水分离材料。聚丙烯酰胺改性后的岩棉为超亲水/水下超疏油性质,可以有效分离汽油、植物油等各种油品与水的混合物。分离过程中,分离效率在97%以上,分离通量超过 $ 15\times10^{3}\ \mathrm{L}/(\mathrm{m}^{2}\cdot\mathrm{h}) $。考虑到高效率、低价格以及易制备等特点,基于岩棉的该过滤材料在现实中的油水分离领域具有广阔的应用前景。
关键词
岩棉;聚丙烯酰胺;超亲水;光引发聚合;油水分离
中图分类号:TB332
文献标志码:A
文章编号:1003-5060(2023)02-0236-05
Preparation of super-hydrophilic/underwater oleophobic filter based on rock wool and its application in oil-water separation
NIE Wei, TONG Qingdong, XU Jian, LI Qianqian, WANG Qiangying, YANG Wen
(School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China)
Abstract
In this study, rock wool was used as the substrate, and polyacrylamide was grafted on the surface of rock wool fiber by light-initiated polymerization to prepare oil-water separation material. The modified rock wool showed super-hydrophilic/underwater oleophobic property, which could effectively separate water mixtures with various oil, such as gasoline and vegetable oil. The separation efficiency was over 97% and the separation flux was beyond $ 15 \times 10^{3} \mathrm{~L}/(\mathrm{m}^{2} \cdot \mathrm{h}) $. Considering the high efficiency, low costs, and easy preparation, this kind of filter based on rock wool has great potential in broad applications in oil-water separation.
Keywords
rock wool; polyacrylamide; super-hydrophilic; light-initiated polymerization; oil-water separation
收稿日期:2020-11-04
修回日期:2020-12-25
基金项目:国家自然科学基金资助项目(21204016);安徽省自然科学基金资助项目(1808085ME112)